Mid-Infrared Laser Generation of Zn1−xMnxSe and Zn1−xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions—Comparison of Different Excitation Wavelengths

Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr2+, Fe2+:Zn1−xMnxSe and Cr2+, Fe2+:Zn1−xMgxSe with similar amounts of manganese or magnesium ions of x ≈ 0.3 were investigated at cryogenic temperatures for three different excitation wavelengths: Q-switched Er:YLF laser at the wavelength of 1.73 μm, Q-switched Er:YAG laser celý popis

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Materials Ročník 15; číslo 15; s. 5277
Hlavní autoři
Říha, Adam, Jelínková, Helena, Doroshenko, Maxim E., Jelínek, Michal, Šulc, Jan, Němec, Michal, Vyhlídal, David, Kovalenko, Nazar O.
Typ dokumentu
Journal Article
Jazyk
English
Vydáno
Basel MDPI AG 30. 07. 2022
MDPI
Témata
Bibliografie
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content type line 23
ISSN
1996-1944
1996-1944
DOI
10.3390/ma15155277
Abstract Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr2+, Fe2+:Zn1−xMnxSe and Cr2+, Fe2+:Zn1−xMgxSe with similar amounts of manganese or magnesium ions of x ≈ 0.3 were investigated at cryogenic temperatures for three different excitation wavelengths: Q-switched Er:YLF laser at the wavelength of 1.73 μm, Q-switched Er:YAG laser at 2.94 μm, and the gain-switched Fe:ZnSe laser operated at a liquid nitrogen temperature of 78 K at ∼4.05 μm. The temperature dependence of spectral and laser characteristics was measured. Depending on the excitation wavelength and the selected output coupler, both laser systems were able to generate radiation by Cr2+ or by Fe2+ ions under direct excitation or indirectly by the Cr2+→ Fe2+ energy transfer mechanism. Laser generation of Fe2+ ions in Cr2+, Fe2+:Zn1−xMnxSe and Cr2+, Fe2+:Zn1−xMgxSe (x ≈ 0.3) crystals at the wavelengths of ∼4.4 and ∼4.8 μm at a temperature of 78 K was achieved, respectively. The excitation of Fe2+ ions in both samples by direct 2.94 μm as well as ∼4.05 μm radiation or indirectly via the Cr2+→ Fe2+ ions’ energy transfer-based mechanism by 1.73 μm radiation was demonstrated. Based on the obtained results, the possibility of developing novel coherent laser systems in mid-IR regions (∼2.3–2.5 and ∼4.4–4.9 μm) based on AIIBVI matrices was presented.
AbstractList Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr2+, Fe2+:Zn1−xMnxSe and Cr2+, Fe2+:Zn1−xMgxSe with similar amounts of manganese or magnesium ions of x ≈ 0.3 were investigated at cryogenic temperatures for three different excitation wavelengths: Q-switched Er:YLF laser at the wavelength of 1.73 μm, Q-switched Er:YAG laser at 2.94 μm, and the gain-switched Fe:ZnSe laser operated at a liquid nitrogen temperature of 78 K at ∼4.05 μm. The temperature dependence of spectral and laser characteristics was measured. Depending on the excitation wavelength and the selected output coupler, both laser systems were able to generate radiation by Cr2+ or by Fe2+ ions under direct excitation or indirectly by the Cr2+→ Fe2+ energy transfer mechanism. Laser generation of Fe2+ ions in Cr2+, Fe2+:Zn1−xMnxSe and Cr2+, Fe2+:Zn1−xMgxSe (x ≈ 0.3) crystals at the wavelengths of ∼4.4 and ∼4.8 μm at a temperature of 78 K was achieved, respectively. The excitation of Fe2+ ions in both samples by direct 2.94 μm as well as ∼4.05 μm radiation or indirectly via the Cr2+→ Fe2+ ions’ energy transfer-based mechanism by 1.73 μm radiation was demonstrated. Based on the obtained results, the possibility of developing novel coherent laser systems in mid-IR regions (∼2.3–2.5 and ∼4.4–4.9 μm) based on AIIBVI matrices was presented.
Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr 2 + , Fe 2 + :Zn 1 − x Mn x Se and Cr 2 + , Fe 2 + :Zn 1 − x Mg x Se with similar amounts of manganese or magnesium ions of x ≈ 0.3 were investigated at cryogenic temperatures for three different excitation wavelengths: Q-switched Er:YLF laser at the wavelength of 1.73 μ m, Q-switched Er:YAG laser at 2.94 μ m, and the gain-switched Fe:ZnSe laser operated at a liquid nitrogen temperature of 78 K at ∼4.05 μ m. The temperature dependence of spectral and laser characteristics was measured. Depending on the excitation wavelength and the selected output coupler, both laser systems were able to generate radiation by Cr 2 + or by Fe 2 + ions under direct excitation or indirectly by the Cr 2 + → Fe 2 + energy transfer mechanism. Laser generation of Fe 2 + ions in Cr 2 + , Fe 2 + :Zn 1 − x Mn x Se and Cr 2 + , Fe 2 + :Zn 1 − x Mg x Se (x ≈ 0.3) crystals at the wavelengths of ∼4.4 and ∼4.8 μ m at a temperature of 78 K was achieved, respectively. The excitation of Fe 2 + ions in both samples by direct 2.94 μ m as well as ∼4.05 μ m radiation or indirectly via the Cr 2 + → Fe 2 + ions’ energy transfer-based mechanism by 1.73 μ m radiation was demonstrated. Based on the obtained results, the possibility of developing novel coherent laser systems in mid-IR regions (∼2.3–2.5 and ∼4.4–4.9 μ m) based on A II B VI matrices was presented.
Author Jelínek, Michal
Vyhlídal, David
Jelínková, Helena
Říha, Adam
Šulc, Jan
Němec, Michal
Doroshenko, Maxim E
Kovalenko, Nazar O
AuthorAffiliation 1 Faculty of Nuclear Sciences and Physical Engineering (FNSPE), Czech Technical University in Prague, Břehová 7, 115 19 Prague, Czech Republic; helena.jelinkova@fjfi.cvut.cz (H.J.); michal.jelinek@fjfi.cvut.cz (M.J.); jan.sulc@fjfi.cvut.cz (J.Š.); michal.nemec@fjfi.cvut.cz (M.N.); david.vyhlidal@fjfi.cvut.cz (D.V.)
2 Prokhorov General Physics Institute, Vavilov Str. 38, 119991 Moscow, Russia; dorosh@lst.gpi.ru
3 Institute for Single Crystals, NAS of Ukraine, Nauky Ave. 60, 61001 Kharkiv, Ukraine; nazar@isc.kharkov.ua
AuthorAffiliation_xml – name: 3 Institute for Single Crystals, NAS of Ukraine, Nauky Ave. 60, 61001 Kharkiv, Ukraine; nazar@isc.kharkov.ua
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– name: 1 Faculty of Nuclear Sciences and Physical Engineering (FNSPE), Czech Technical University in Prague, Břehová 7, 115 19 Prague, Czech Republic; helena.jelinkova@fjfi.cvut.cz (H.J.); michal.jelinek@fjfi.cvut.cz (M.J.); jan.sulc@fjfi.cvut.cz (J.Š.); michal.nemec@fjfi.cvut.cz (M.N.); david.vyhlidal@fjfi.cvut.cz (D.V.)
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Snippet Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr2+, Fe2+:Zn1−xMnxSe and Cr2+, Fe2+:Zn1−xMgxSe with similar amounts of...
Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr 2 + , Fe 2 + :Zn 1 − x Mn x Se and Cr 2 + , Fe 2 + :Zn 1 − x Mg x Se with...
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StartPage 5277
SubjectTerms Bridgman method
Chromium
Cryogenic temperature
Crystals
Energy
Energy transfer
Excitation
Infrared lasers
Iron
Lasers
Liquid nitrogen
Magnesium
Manganese
Q switched lasers
Radiation
Semiconductor lasers
Single crystals
Solid solutions
Spectrum analysis
Temperature dependence
Wavelengths
YAG lasers
YLF lasers
Zinc
Title Mid-Infrared Laser Generation of Zn1−xMnxSe and Zn1−xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions—Comparison of Different Excitation Wavelengths
URI https://www.proquest.com/docview/2700746199
https://search.proquest.com/docview/2702188261
https://pubmed.ncbi.nlm.nih.gov/PMC9369922
Volume 15
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